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AAS
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See: Atomic
Absorption Spectroscopy.
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Abatement
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Reduce the quantity or toxicity
of waste being generated by modifications to
the process and by recycling.
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Abraded grain
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Grain
enamel that has been damaged by bacterial, mechanical
or chemical action. See: Low
grain, blind grain.
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Abrasion
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Removal of surface
material from any solid through the frictional
action of another solid, a liquid, a gas, or
combination thereof.
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Abrasive paper
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Paper coated with abrasive powder
used for machine buffing of leather.
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Abscess
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Localised
infection over lesions in the skin or hide,
sometimes covered with a scab.
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Absorptive power
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Capability of a material (dye,
levelling agent, grease) to be taken up by the
fabric.
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Acer tannin
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Crystalline digalloyl hexitol,
without tanning properties, isolated from the
leaves of Acer ginnala.
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Acid dyestuff
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Water-soluble anionic dyestuff
that is applied to nitrogenous fibres such as
leather, wool, silk, nylon and modified acrylic
fibres from acid or neutral baths.
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Acid tan
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Partially spent vegetable tanning
material, removed from the old-fashioned layer
pits , which has become acid owing to fermentation
and is leached to prepare suspender liquors.
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Acid residue
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Part of an acid linked
in a compound.
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Acid-salt ratio
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Ratio of total salts to total
free acids in a vegetable tan liquor.
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Acrylic binder
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Thermoplastic binder based on
polyacrylates. Used as film-forming material
for polymer or binder finishes.
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Additive
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General term for all auxiliaries
used in finish formulations.
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Adhesion
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Measure
of the ability of a film of finish to resist
being peeled away from the surface of the leather
to which it has been applied.
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Adhesive
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Substance used to
bond two or more solids so that they act or
can be used as a single piece; examples are
resins, glue, paste, cement, putty and polyvinyl
resin emulsions.
In the footwear industry
it is known as cement and it is used to bond
the outsole or linings to the upper.
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Adhesive power
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Ability of a finish to hold firmly
onto the leather or another coating.
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Adhesive strip test
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Empiric evaluation
of the adhesion of the finishing layer by applying
a strip of adhesive paper on the finished surface
of the leather and tearing it away rapidly.
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Adipose tissue
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Form of connective tissue in
whose cell fat is deposited and stored. More
frequently found in the flesh layer of the hide or skin.
See: Double hiding; fatty spue;
fatty stain; grease mark; degrease (v); degreasing.
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Adsorbable Organic Halogens Compounds (AOX)
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Chemical organic halogen compounds
that are adsorbed to surfaces or materials.
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Adsorption
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Retention of molecules or substances
on the surface of a solid. Pollutant elements
can be adsorbed. Should not be confused with
absorption.
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Aerated lagooning
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A biological process for treating
wastewater by sending it to a basin or lagoon
that is aerated to ensure an oxygen supply sufficient
for biological purification. A distinction is
drawn between strict aerobic lagoons and facultative
aerobic lagoons. In the first, all sedimentation
is avoided by maintaining a high enough level
of aeration. In the second, the oxygen input
ensures biological activity but cannot keep
all of the matter present suspended.
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Aeration
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Introduction of oxygen into water
or effluent streams by bringing the water or
effluent into intimate contact with air.
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Aeration tank
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Tank in which aeration is performed
for the biological aerobic treatment of an effluent.
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Aerator
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Surface aerator intended to aerate
water through a surface mixing. The two main
types are :
- vertical axis type (takes water
and sprays it laterally into the air)
- horizontal axis type (sweeps
the water with a submerged portion of blades).
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Aerobic sludge digestion
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Describes a condition in which
dissolved oxygen is present.
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Aerobiosis
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A biological process in which
the presence of dissolved oxygen is necessary
for the respiration of the micro-organisms.
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Agate cylinder
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Glazing cylinder in a glazing
machine to develop a high gloss to previously
seasoned leather.
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Ageing
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1. To store leather
to allow tanning agent to become more firmly
fixed.
2. Changes that occur during the use of the
material over a period of time. For example,
caused by heat, ultra violet or artificial ageing
processes.
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Agent
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Generic term covering many different
materials used in processing hides and skins
through to finished leather.
See: Levelling agent; fixing
agent.
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Air blast
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Blowing (in) compressed air,
such as air-blast dedusting machine.
See: Dedust (v); dedusting.
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Air bubbles
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Entrapped
air beneath the finish surface.
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Air circulation
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System of circulating air continuously
round a drying unit, often for several times,
before being extracted.
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Air drying
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Drying of hides, skins or finished
leather by exposure to the air until equilibrium
is reached.
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Air permeability
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Ability of a membrane
or other material to permit air to pass through
it.
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Air scrubber
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Device used to purify the air
with circulating water, such as used in automatic
spraying machine cabinets.
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Airless spraying
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Application technique of finish.
In this system the liquid finish is ejected
from the spray gun under pressure without air,
giving a much heavier spray coat with less bounce-off
or waste.
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Albumin
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Any of a group of
plant and animal proteins which are soluble
in water and dilute salt solutions and are coagulated
by heat.
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Alcohol
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General term for different alcohols,
organic chemical compounds containing the -OH
group, used in finish formulations as solvents
or diluents.
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Aldehyde
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One of a class of
organic compounds containing the -CHO group.
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Aldehyde retannage
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Second tanning treatment, with
an aldehyde R-CHO, of an already tanned leather,
to modify its properties, using an agent of
the same or an entirely different type.
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Aldehyde tannage
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Tannage with an aldehyde, such
as glutaraldehyde or modified glutaraldehyde,
usually in combination with other tanning materials.
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Alkali
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Any chemical (salt or mixture)
that neutralises acids.
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Alkyl phenol ethoxylates (APE)
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Chemical group which includes
nonyl phenol ethoxylates such as emulsifiers.
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Alkylation
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Chemical process
in which an alkyl radical is introduced into
an organic compound by substitution or addition.
For example, if the -CH3 group is introduced the process is defined
methylation.
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Alum retanned
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Second tanning treatment, with
double sulphates formed from one of the alkali
metals combined with a trivalent metal, usually
potassium alum and salt, but sometimes with
aluminium sulphate and salt.
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Alum tanning
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Process of converting skins to
leather based essentially upon the use, strictly
speaking, of potassium alum, but sometimes of
aluminium sulphate.
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Aluminium tanned
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Converted to leather with an
aluminium salt.
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Amine unhairing
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Removal of hair or wool from
hides or skins by amines.
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Amino acid
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Any of the organic
compounds that contain one or more basic amino
groups and one or more acidic carboxyl groups.
Many amino acids are polymerised to form peptides
and proteins; examples are tyrosine and lysine.
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Amphoteric dyestuff
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Dyestuff which can exhibit the
characteristics of either an acid or a base,
and could ionise as a coloured cation or anion,
according to the pH.
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Amphoteric tannin
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Synthetic organic tanning agent,
prepared by condensation of polyhydroxyphenols
with aldehydes and bases, possessing both basic
groups and acid phenolic groups; acts in acid
solution as a cationic tannin.
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Anaerobic sludge digestion
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Biological reaction for sludge
under anaerobic condition (lack of oxygen),
producing mainly methane (CH4) and
C02 and stabilised sludge.
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Anaerobiosis
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A biological process in which
the reactions occur in the absence of dissolved
oxygen; only chemically bound oxygen is used
for the respiration of the micro-organisms.
This species of micro-organisms is said to be
anaerobic.
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Angle of weave
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Fibre
pattern within the hide or skin. Can be genetic
or process related. Horizontal fibre defect
is where the corium fibres are orientated horizontal
to the grain surface and are parallel and not
interlaced. Vertical fibre defect is where fibres passing from
the epidermal layer to the corium are orientated
vertically to the grain surface.
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Aniline
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Colourless oily compound, C6H5
NH2, the base used in the formation
of many rich dyes obtained from coal tar but
more extensively from benzole; also the base
for resins and varnishes.
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Aniline dye
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Synthetic dye based on aniline.
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Aniline finish
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Dyed leather without any pigmented
coat. A transparent top coat may be added but
the natural appearance of the grain should remain
visible.
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Anionic dyestuff
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Ion, molecule or radical from
a dyestuff with a negative charge.
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Anionic fatliquor
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Ion, molecule or radical from
a fatliquor (oil globules) with a negative charge.
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Anionic resin
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Ion, molecule or radical from
a resin (organic substance) with a negative
charge.
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Anionic surfactant
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Ion, molecule or radical from
a surfactant with a negative charge.
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Anoxia
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Describes a condition in which
oxygen is absent and where nitrites and nitrates
are present.
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Ante mortem
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1. Made shortly before death,
for instance injuries in the slaughterhouse
during unloading from the transporting trucks,
etc.
2. Ante mortem is very often
used to designate skin and hide damage factors
occurring ‘long’ before the animals death.
Note: Health issues such as ectoparasites.
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Anti-auxochrome group
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Any radical or group, such as
–NO, -NO2 or C=O, in a coloured organic
substance which can accept electrons.
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Anti-friction agent
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Finishing auxiliary such as silicone
based modifiers, used to improve the surface
feel of the leather. Note: Silky, slippy feel
to garment leather.
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Antique grain
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Finishing method for achieving
irregular two-tone effects to give the grain
side of the leather an appearance of age and
usage. The leather receives a raised embossed
grain and after application of a wax resist
it is treated with a second, mostly darker graining
colour. The recessed parts will then have a
darker shade in comparison to the raised parts.
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Antiseptic
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Compound that can be applied
to and remain on the surface of the skin or
mucosa and kill or inhibit the growth of infection-causing
micro-organisms.
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Anti-sticking agent
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Used to reduce tackiness of the
finishing coat and assist hot plating, embossing
or ironing.
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AOX
|
See: Adsorbable Organic Halogens
Compounds.
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APE
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See: Alkyl phenol ethoxylate.
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Apparel leather
|
See: Clothing leather.
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Apparent density
|
Ratio between the
mass and the volume of a substance including
both the structure and the enclosed air spaces.
Note: The interfibrillary spaces between fibres
in the leather.
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Apron leather
|
Leather for protective aprons
for smiths, foundry workers, draymen, etc.
Note: Vegetable or chrome tanned,
stout, large sheep and pigskins, kips and cattle
hide splits.
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Aqueous emulsion
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Dispersion of one liquid, such
as oil, throughout water in which it is insoluble.
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Area contraction
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Shrinkage in the
area of a leather.
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Area loss
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See: Area contraction.
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Area measurement
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Measurement of the
area of a leather or hide or skin. The area
is expressed in m2 (square metres)
or in dm2 (square decimetres). The
traditional method, still widely used, is to
express the area in square feet (sq. ft. = 30.48
x 30.48 cm2).
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Aromatic amine
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Organic compound
that contains one or more amino groups joined
to an aromatic structure.
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Artificial grain
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Grain appearance
given to a flesh split or buffed grain by pigment
finishing with or without embossing.
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Aryl amine
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See: Aromatic amine.
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ASA-leather
|
In Austria and Germany the common
abbreviation for leather for the production
of protective articles used in leather industry
(Arbeiter-Schutzartikel=ASA), usually made of
chrome tanned cattle hide leather.
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Ash
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Residue of a material after total
combustion. It is generally used to characterise
a solid waste and is expressed in % of the raw
material.
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Assortment
|
Collection of hides or skins
having approximately the same desired characteristics.
Note: Weight, freedom of defects.
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Astringency
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Property of a tanning
agent to combine rapidly with the hide substance,
leading to a contraction of the structure of
the hide. This term is often used to describe
the properties of a vegetable tanning solution.
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Atomic Absorption Spectroscopy (AAS )
|
Measurement of the
concentration of a metal ion in a solution.
It is the measurement of the amount of a light
energy of a known wavelength absorbed by the
metal atoms vaporised in a flame. The wavelength
of the light to be used is specific for each
metal. The measurement is independent of the
ionic form of the metal in the solution.
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Auto inflammation temperature
|
Minimum temperature at which
a liquid can inflame without additional energy.
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Autolysis
|
Self-digestion
process, causing damage to the hide structure
due to enzyme action and occurring if curing
is delayed too long after flaying.
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Automotive leather
|
Upholstery leather for car seats
and other internal parts of the interior design.
Note: These leathers must meet
specific requirements, such as fogging tests.
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Auxiliary (synthetic) tannin
|
Synthetic tannin not suitable
for use alone as a tanning agent, but designed
for use with vegetable tannins to assist tannage,
for instance to accelerate penetration, or to
improve the leather, such as its colour.
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Auxochrome group
|
Group, such as –NH2
or –OH, in a coloured organic substance which
can donate electrons; any of certain radicals,
which will convert a chromophore into an acidic
or basic dye suitable for use in leather and
textile fabrics.
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Azo dye
|
Dye produced on the basis of
an aromatic amine.
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